Nested Keplerian architecture of [Cu58H20(SPr)36(PPh3)8]2+ nanoclusters

Author:

Biswas Sourav1ORCID,Hossian Sakiat1ORCID,Kosaka Taiga1,Sakai Jin1,Arima Daichi2,Niihori Yoshiki1ORCID,Mitsui Masaaki2ORCID,Jiang De-en3ORCID,Das Saikat1ORCID,Wang Song4,Negishi Yuichi1ORCID

Affiliation:

1. Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan

2. Department of Chemistry, College of Science, Rikkyo University, Toshima-ku, Tokyo 171-8501, Japan

3. Department of Chemical and Biomolecular Engineering and Department of Chemistry, Vanderbilt University, Nashville, TN 37235, USA

4. Hefei National Research Center for Physical Sciences at the Microscale, School of Chemistry and Materials Science, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China

Abstract

The composition of the structure consists of a series of five concentric polyhedra comprising Cu(i) atoms, along with an additional set of five concentric polyhedra composed of ligands spanning a distance of 2 nm.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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