Anomeric alkylations and acylations of unprotected mono- and disaccharides mediated by pyridoneimine in aqueous solutions-Reference-Cited by-同舟云学术

Anomeric alkylations and acylations of unprotected mono- and disaccharides mediated by pyridoneimine in aqueous solutions

Published:2022 Issue:13 Volume:58 Page:2224-2227
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Dey Kalyan¹,Jayaraman Narayanaswamy¹^ORCID

Affiliation:

1. Indian Institute of Science, Bangalore 560012, India

Abstract

Pyridoneimine-mediated site-specific deprotonation of the hemiacetal moiety of several mono-, disaccharides in aq. solutions and the reactions of which with alkylating and acylating agents, leading to alkyl glycosides and sugar esters, is reported.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D1CC07056H

Reference51 articles.

1. Stereocontrolled Glycosyl Transfer Reactions with Unprotected Glycosyl Donors

2. Strategies toward protecting group-free glycosylation through selective activation of the anomeric center

3. Anomeric modification of carbohydrates using the Mitsunobu reaction

4. Chemoselective Reactions for the Synthesis of Glycoconjugates from Unprotected Carbohydrates

5. Transition-State Structure for the Quintessential SN2 Reaction of a Carbohydrate: Reaction of α-Glucopyranosyl Fluoride with Azide Ion in Water

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