Regulating the solvation structure of an acetonitrile-based electrolyte for Li/NMC811 batteries cycled at low temperature

Author:

Liu Lin1,Shadike Zulipiya1ORCID,Cai Xinyin1,Hong Mengwei1,Gao Yue2,Shen Shuiyun1,Zhang Junliang1ORCID

Affiliation:

1. Institute of Fuel Cells, School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

2. State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai, 200433, China

Abstract

An acetonitrile-based localized high concentration electrolyte has been developed for low temperature lithium metal batteries. The corresponding Li/NMC811 cell delivers a high capacity of 113 mA h g−1 at −40 °C with 85.5% capacity retention.

Funder

National Key Research and Development Program of China

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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