Ambient and high-pressure kinetic investigation of methanol substitution in fac-[Re(Trop)(CO)3(MeOH)] by different monodentate nucleophiles-Reference-Cited by-同舟云学术

Ambient and high-pressure kinetic investigation of methanol substitution in fac-[Re(Trop)(CO)3(MeOH)] by different monodentate nucleophiles

Published:2019 Issue:27 Volume:48 Page:9984-9997
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Schutte-Smith Marietjie¹²³⁴⁵^ORCID,Roodt Andreas¹²³⁴⁵^ORCID,Visser Hendrik G.¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. University of the Free State

3. PO Box 339

4. Bloemfontein

5. South Africa

Abstract

First report of high-pressure methanol substitution by entering monodentate L forms fac-[Re(CO)₃(Trop)(L)] {ΔV^≠_(kL) = +9 – +14 cm⁻³ mol⁻¹}, indicating dissociative/dissociative interchange activation.

Funder

Universiteit van die Vrystaat

Sasol

National Research Foundation

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT01528K

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