A new approach to fabricate the Mn(ii)-based magnetic refrigerant through incorporation of a diamagnetic {LiO4} spacer-Reference-Cited by-同舟云学术

A new approach to fabricate the Mn(ii)-based magnetic refrigerant through incorporation of a diamagnetic {LiO4} spacer

Published:2018 Issue:7 Volume:47 Page:2143-2147
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Wu Jia-Wei¹²³⁴⁵,Wang Xue⁶³⁷⁸,Tian Chong-Bin¹²³⁴⁵,Du Shao-Wu¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Structural Chemistry

2. Fujian Institute of Research on the Structure of Matter

3. Chinese Academy of Sciences

4. Fujian

5. Fuzhou 350002

6. Yantai Branched Center of Shandong Technology Transfer Center

7. Yantai 264000

8. P. R. China

Abstract

We synthesized a new 3D MOF composed of 1D heterometallic inorganic Mn(ii)–Li(i) chains in which the paramagnetic Mn(ii) ions were separated by diamagnetic {LiO₄} connectors. It shows a significant MCE with −ΔS_m of 30.4 J kg⁻¹ K⁻¹ for ΔH = 8 T at 2 K.

Funder

National Natural Science Foundation of China

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C7DT04820C

Reference62 articles.

1. Molecule-based magnetic coolers

2. Recent advances in the design of magnetic molecules for use as cryogenic magnetic coolants