Oxygen reduction reaction (ORR) in alkaline solution catalysed by an atomically precise catalyst based on a Pd(<scp>ii</scp>) complex supported on multi-walled carbon nanotubes (MWCNTs). Electrochemical and structural considerations-Reference-Cited by-同舟云学术

Oxygen reduction reaction (ORR) in alkaline solution catalysed by an atomically precise catalyst based on a Pd(ii) complex supported on multi-walled carbon nanotubes (MWCNTs). Electrochemical and structural considerations

Published:2024 Issue: Volume: Page:
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Monini Valeria¹,Bonechi Marco¹^ORCID,Bazzicalupi Carla¹^ORCID,Bianchi Antonio¹²^ORCID,Gentilesca Pietro¹^ORCID,Giurlani Walter¹,Innocenti Massimo¹²^ORCID,Meoli Arianna¹,Romano Giammarco Maria¹^ORCID,Savastano Matteo²³^ORCID

Affiliation:

1. Department of Chemistry “Ugo Schiff”, University of Florence, Via della Lastruccia 3-13, 50019 Sesto Fiorentino, Italy

2. National Interuniversity Consortium of Materials Science and Technology (INSTM), Research Unit of Florence, Via G. Giusti 9, 50121 Florence, Italy

3. Department of Human Sciences for the Promotion of Quality of Life, University San Raffaele Roma, Via di Val Cannuta 247, 00166 Rome, Italy

Abstract

Apical interaction of O2 with a square planar macrocyclic Pd(ii) complex anchored on MWCNTs gives rise to a significant electrocatalytic activity towards the oxygen reduction reaction (ORR). This finding confirms previous computational data.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D3DT03947A

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