Competing dynamics of intramolecular deactivation and bimolecular charge transfer processes in luminescent Fe(<scp>iii</scp>) N-heterocyclic carbene complexes-Reference-Cited by-同舟云学术

Competing dynamics of intramolecular deactivation and bimolecular charge transfer processes in luminescent Fe(iii) N-heterocyclic carbene complexes

Published:2023 Issue:13 Volume:14 Page:3569-3579
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Rosemann Nils W.¹²^ORCID,Lindh Linnea²³^ORCID,Bolaño Losada Iria³^ORCID,Kaufhold Simon⁴^ORCID,Prakash Om⁴^ORCID,Ilic Aleksandra⁴^ORCID,Schwarz Jesper⁴^ORCID,Wärnmark Kenneth⁴^ORCID,Chábera Pavel²^ORCID,Yartsev Arkady²^ORCID,Persson Petter³^ORCID

Affiliation:

1. Light Technology Institute, Karlsruhe Institute of Technology, Engesserstraße 13, DE-76131 Karlsruhe, Germany

2. Department of Chemical Physics, Lund University, Box 124, SE-22100 Lund, Sweden

3. Department of Theoretical Chemistry, Lund University, Box 124, SE-22100 Lund, Sweden

4. Centre for Analysis and Synthesis, Department of Chemistry, Lund University, Box 124, SE-22100 Lund, Sweden

Abstract

Deactivation of an excited FeIII based dye has been investigated. Intramolecular deactivation is comparable to organic dyes, and ultrafast intermolecular deactivation via photoinduced disproportionation is observed over a range of low temperatures.

Funder

Stiftelsen för Strategisk Forskning

Knut och Alice Wallenbergs Stiftelse

Vetenskapsrådet

Alexander von Humboldt-Stiftung

Energimyndigheten

Sten K Johnsons stiftelse

Wenner-Gren Stiftelserna

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry