Azo-oximate metal-carbonyl to metallocarboxylic acid <i>via</i> the intermediate Ir(<scp>iii</scp>) radical congener: quest for co-ligand driven stability of open- and closed-shell complexes-Reference-Cited by-同舟云学术

Azo-oximate metal-carbonyl to metallocarboxylic acid via the intermediate Ir(iii) radical congener: quest for co-ligand driven stability of open- and closed-shell complexes

Published:2022 Issue:26 Volume:51 Page:10121-10135
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Dinda Soumitra¹^ORCID,Pramanik Shuvam²^ORCID,Basu Jaydeep¹^ORCID,Patra Sarat Chandra²^ORCID,Pramanik Kausikisankar²^ORCID,Ganguly Sanjib¹^ORCID

Affiliation:

1. Department of Chemistry, St. Xavier's College (Autonomous), Kolkata – 700016, India

2. Department of Chemistry, Jadavpur University, Kolkata 700032, India

Abstract

Radical-mediated conversion of metal carbonyl to metallocarboxylic acid has been successfully accomplished along with the exploration of the stability of open- and closed-shell complexes by stereochemical alteration of co-ligands.

Funder

Department of Science and Technology, Ministry of Science and Technology, India

Department of Biotechnology, Ministry of Science and Technology, India

Council of Scientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT00345G

Reference113 articles.

1. Non-innocent ligands in bioinorganic chemistry—An overview