Affiliation:
1. Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, 123 Bevier Road, Piscataway, New Jersey 08854, USA
Abstract
A cobalt–phenylenediamide complex reacts with electrophilic CF3+ and F+ sources, generating new Co(iii)–CF3 or Co(iii)–F species through ligand-to-substrate two-electron transfer.
Funder
American Chemical Society Petroleum Research Fund
National Science Foundation
Rutgers, The State University of New Jersey
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis