New insight into the catalytic mechanism of ester hydrogenation over the Cu/ZnO catalyst: the contribution of hydrogen spillover-Reference-Cited by-同舟云学术

New insight into the catalytic mechanism of ester hydrogenation over the Cu/ZnO catalyst: the contribution of hydrogen spillover

Published:2024 Issue:9 Volume:53 Page:4048-4053
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Gao Lin¹²³,Ding Guoqiang³,Zhu Lei³,Yu Zhanqiu³,Li Hongju³,Li Guoqiang⁴,Zhu Yulei¹³^ORCID,Xiang Hongwei¹³,Wen Xiaodong¹³^ORCID,Yang Yong¹³^ORCID,Li Yongwang³

Affiliation:

1. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, PR China

2. University of Chinese Academy of Sciences, Beijing, 100049, PR China

3. Synfuels China Co. Ltd, Beijing, PR China

4. Synfuels China Inner Mongolia Technology Research Institute Co., Ltd, Ordos, PR China

Abstract

Cu+ZnO-X catalysts exhibit a synergistic effect in ester hydrogenation due to the strong adsorption of ester groups by ZnO and H2 activation by metallic Cu, with a proposed mechanism involving hydrogen spillover.

Funder

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D3DT04268E

Reference34 articles.

1. Hydrogenation of dimethyl malonate to 1,3-propanediol catalyzed by a Cu/SiO2 catalyst: the reaction network and the effect of Cu+/Cu0 on selectivity

2. Selective hydrogenation of dimethyl maleate to tetrahydrofuran over Cu/SiO2 catalyst: Effect of Cu+ on the catalytic performance

3. Supported Pt-Re catalysts for the selective hydrogenation of methyl and ethyl esters to alcohols

4. Selective hydrogenation of fatty acids and methyl esters of fatty acids to obtain fatty alcohols-a review

5. Catalytic transfer hydrogenation of levulinate ester into γ-valerolactone over ternary Cu/ZnO/Al2O3 catalyst

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