Water oxidation by a dye-catalyst diad in natural sunlight: timing and coordination of excitations and reactions across timescales of picoseconds to hours-Reference-Cited by-同舟云学术

Water oxidation by a dye-catalyst diad in natural sunlight: timing and coordination of excitations and reactions across timescales of picoseconds to hours

Published:2023 Issue:8 Volume:14 Page:1997-2008
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Massad Ramzi N.¹²^ORCID,Cheshire Thomas P.²^ORCID,Fan Chenqi¹²^ORCID,Houle Frances A.²^ORCID

Affiliation:

1. College of Chemistry, University of California, Berkeley, Berkeley, CA 94720, USA

2. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA

Abstract

Excitations and reactions in a dye−catalyst dyad for solar-driven water oxidation have timing mismatches caused by the stochastics of some catalytic steps. Rather than being perfectly meshed, these processes are like gears with missing teeth.

Funder

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D2SC06966K

Reference49 articles.

1. Hybrid Photoelectrochemical Water Splitting Systems: From Interface Design to System Assembly

2. Water splitting dye-sensitized solar cells

3. Artificial photosynthesis: opportunities and challenges of molecular catalysts

4. Ostwald Isolation to Determine the Reaction Order for TiO2(e–)|S+→ TiO2|S Charge Recombination at Sensitized TiO2 Interfaces

5. A High-Valent Metal-Oxo Species Produced by Photoinduced One-Electron, Two-Proton Transfer Reactivity

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