Regulating polystyrene glass transition temperature by varying the hydration levels of aromatic ring/Li+ interaction

Author:

Chin Sze Yuet1,Lu Yunpeng2,Di Weishuai3,Ye Kai4,Li Zihan5,He Chenlu6ORCID,Cao Yi37,Tang Chun5ORCID,Xue Kai18ORCID

Affiliation:

1. NTU Center of High Field NMR Spectroscopy and Imaging, Nanyang Technological University, 21 Nanyang Link, 637371, Singapore

2. School of Chemistry, Chemical Engineering and Biotechnology, Nanyang Technological University, 21 Nanyang Link, 637371, Singapore

3. Collaborative Innovation Center for Advanced Microstructures, National Laboratory of Solid State Microstructure, Department of Physics, Nanjing University, Nanjing 210093, People's Republic of China

4. School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore, 639789, Singapore

5. Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking-Tsinghua Center for life Sciences, Center for Quantitative Biology, Academy for Advanced Interdisciplinary Studies, Peking University, Beijing 100871, China

6. Department of Chemistry, National University of Singapore, Singapore, 117549, Singapore

7. Institute for Brain Sciences, Nanjing University, Nanjing 210023, People's Republic of China

8. School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, 637371, Singapore

Abstract

Cation–π interactions can be tailored with different hydration levels of the ion, and leads to a variation of polymer properties. Proton detected solid state NMR provides important insights in this field.

Funder

Ministry of Education - Singapore

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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