Directed C8–H allylation of quinoline <i>N</i>-oxides with vinylcyclopropanes <i>via</i> sequential C–H/C

Directed C8–H allylation of quinoline N-oxides with vinylcyclopropanes via sequential C–H/C–C activation

Published:2023 Issue:19 Volume:59 Page:2823-2826
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Mandal Santu¹,Karjee Pallab¹^ORCID,Saha Sharajit¹,Punniyamurthy Tharmalingam¹^ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati-781039, India

Abstract

The Rh(iii)-catalyzed C8-selective allylation of quinoline N-oxides has been achieved with vinylcyclopropanes as the allyl source with an excellent (E)-diastereocontrol at room temperature via sequential C–H and C–C activation.

Funder

Science and Engineering Research Board

Department of Science and Technology, Ministry of Science and Technology, India

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D2CC06646G

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