Synthesis of 1,4-Epoxy-2-aryltetrahydro-1-benzazepines via Rhodium(III)-Catalyzed C-H Allylation/Intramolecular 1,3-Dipolar Cycloaddition
-
Published:2024
Issue:
Volume:
Page:
-
ISSN:1359-7345
-
Container-title:Chemical Communications
-
language:en
-
Short-container-title:Chem. Commun.
Author:
Wang Xuan,Li Jianlong,Du Haifang,Liang Weihong,Luo Cheng,Wu Yunshan,Liu Bo
Abstract
Herein, we report a new synthetic route to 1,4-epoxy-2-aryltetrahydro-1-benzazepine derivatives with high efficiency, namely the Rh(III)-catalyzed C-H allylation of nitrones with allyl precursor, followed by subsequent intramolecular 1,3-dipolar cycloaddition, to...
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis