Tuning the spin crossover behavior of the polyanion [(H2O)6Fe3(μ-L)6]6–: the case of the cesium salt
Author:
Affiliation:
1. Institute of Chemical Research of Catalonia (ICIQ)
2. The Barcelona Institute of Science and Technology (BIST)
3. 43007 Tarragona
4. Spain
5. ICREA
Abstract
Cation exchange transforms the gradual spin transition of the trimer [(H2O)6Fe3(μ-L)6]6– into an abrupt transition with a wide hysteresis above room temperature.
Funder
Secretaría de Estado de Investigación, Desarrollo e Innovación
Generalitat de Catalunya
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT01339J
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