Unveiling the significance of adduct formation between thiocarbonyl Lewis donors and diiodine for the structural organization of rhodanine-based small molecule semiconductors-Reference-Cited by-同舟云学术

Unveiling the significance of adduct formation between thiocarbonyl Lewis donors and diiodine for the structural organization of rhodanine-based small molecule semiconductors

Published:2024 Issue:30 Volume:12 Page:11352-11360
ISSN:2050-7526
Container-title:Journal of Materials Chemistry C
language:en
Short-container-title:J. Mater. Chem. C

Author:

Sanna Anna Laura¹^ORCID,Acca Simone¹,Podda Enrico²^ORCID,Mascia Antonello³^ORCID,Pintus Anna¹^ORCID,Aragoni M. Carla¹^ORCID,Lippolis Vito¹^ORCID,Ricci Carlo⁴,Cosseddu Piero³^ORCID,Arca Massimiliano¹^ORCID,Sforazzini Giuseppe¹^ORCID

Affiliation:

1. Department of Chemical and Geological Sciences, University of Cagliari, S.P. no. 8 km 0.700, Monserrato 09042, Cagliari, Italy

2. Centro Servizi di Ateneo per la Ricerca - CeSAR, University of Cagliari, S.P. no. 8 Km 0.700, Monserrato 09042, Cagliari, Italy

3. Department of Electrical and Electronic Engineering, University of Cagliari, Piazza d’Armi, Cagliari 09123, Italy

4. Department of Physics, University of Cagliari, S.P. no. 8 Km 0.700, 09042, Monserrato, CA, Italy

Abstract

Rhodanine vinyl bithiophene was reacted with molecular iodine to give a 1 : 1 stoichiometric charge-transfer adduct whose crystals, structurally and spectroscopically characterized, exhibited remarkable stability and enhanced conductivity.

Funder

Programma Operativo Nazionale Ricerca e Competitività

Fondazione di Sardegna

Ministero della transizione ecologica

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/TC/D4TC01791A

Reference67 articles.

1. Highly Ordered Small Molecule Organic Semiconductor Thin-Films Enabling Complex, High-Performance Multi-Junction Devices

2. Charge transport in high-mobility conjugated polymers and molecular semiconductors

3. The Polymer Physics of Multiscale Charge Transport in Conjugated Systems

4. Influence of intermolecular interactions of electron donating small molecules on their molecular packing and performance in organic electronic devices

5. Role of Intermolecular Interactions in Molecular Packing of Alkoxy-Substituted Bis-1,3,4-oxadiazole Derivatives