Circularly polarized luminescence and high photoluminescence quantum yields from rigid 5,10-dihydroindeno[2,1-a]indene and 2,2′-dialkoxy-1,1′-binaphthyl conjugates and copolymers

Author:

Iwata Keisuke1,Tsurui Makoto2,Itaya Kosuke2,Hamaguchi Naoto1,Egawa Yasunobu1,Kitagawa Yuichi2ORCID,Hasegawa Yasuchika2ORCID,Tsuji Hayato1ORCID

Affiliation:

1. Department of Chemistry, Faculty of Science, Kanagawa University, 3-27-1 Rokkaku-bashi, Kanagawa-ku, Yokohama 221-8686, Japan

2. Faculty of Engineering, Hokkaido University, Kita13 Nishi8, Kita-ku, Sapporo 060-8628, Japan

Abstract

Rigid planar carbon-bridged oligo(phenylenevinylene)–binaphthyl conjugates and alternating copolymers exhibit high luminescence quantum yield of >0.95, along with circular polarized luminescence dissymmetry factors of up to 1.1 × 10−3.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

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