Transformation of thiols to disulfides <i>via</i> an oxidant-free radical pathway on the zeolite ETS-10-Reference-Cited by-同舟云学术

Transformation of thiols to disulfides via an oxidant-free radical pathway on the zeolite ETS-10

Published:2022 Issue:23 Volume:24 Page:9033-9039
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Zhu Chaojie¹,Wu Dongfang¹,Liu Huili²,Meng Congwei²,Tang Tiandi²^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Southeast University, Nanjing, Jiangsu 211189, P. R. China

2. Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical Engineering, Changzhou University, Changzhou, Jiangsu 213164, P. R. China

Abstract

Thiols adsorb and coordinate with the O atom in a –Ti–O–Ti– unit and an electron is transferred from the O to the S atom, leading to the generation of sulfur and hydrogen radicals via S–H bond homolysis followed by dimerization to disulfides and H2.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/GC/D2GC02894H

Reference63 articles.

1. A new electrochemical method of preparation of unsymmetrical disulfides

2. Rhodium-Catalyzed Disulfide Exchange Reaction

3. Phosphine-free cationic rhodium(I) complex-catalyzed disulfide exchange reaction: convenient synthesis of unsymmetrical disulfides