The formation of cage phosphoranes and their rearrangements in the reactions of substituted 2-(3-oxo-3-phenyl)ethoxybenzo[d]-1,3,2-dioxaphospholes with perfluorodiacetyl-Reference-Cited by-同舟云学术

The formation of cage phosphoranes and their rearrangements in the reactions of substituted 2-(3-oxo-3-phenyl)ethoxybenzo[d]-1,3,2-dioxaphospholes with perfluorodiacetyl

Published:2021 Issue:68 Volume:57 Page:8516-8519
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Mironov Vladimir F.¹²^ORCID,Dimukhametov Mudaris N.¹,Ivkova Gulnara A.²^ORCID,Khayarov Khasan R.²,Islamov Daut R.¹²^ORCID,Litvinov Igor A.¹^ORCID

Affiliation:

1. A.E.Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, Arbuzov Str. 8, Kazan 420088, Russia

2. Kazan (Volga Region) Federal University, Kremlevskaya Str. 18, Kazan 420008, Russia

Abstract

Unexpected Kukhtin–Ramirez reaction mechanism of compound I with perfluorodiacetyl was found. The process proceeded via the [4+4]-cycloaddition forming cage species II, which further rearranged through spirophosphorane III into cage phosphorane IV.

Funder

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC02941J

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