Simultaneous discovery of chiral and achiral dyes: elucidating the optical functions of helical and flag-hinged boron tetradentate complexes

Author:

Cui Luxia1ORCID,Furuta Ryoji1,Harada Takunori2ORCID,Konta Takeru2,Hoshino Yu13ORCID,Ono Toshikazu13ORCID

Affiliation:

1. Department of Applied Chemistry, Graduate School of Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan

2. Faculty of Science and Technology, Graduate School of Engineering, Oita University, 700 Dannoharu, Oita City 870-1192, Japan

3. Center for Molecular Systems (CMS), Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan

Abstract

Coordination-induced two boron families were simultaneously achieved. One B–O–B bridged complex exhibits a helical conformation for chiroptical response. Utilizing dimethylaminobenzene as a proton sensor endows luminescence color/intensity change.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

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