Quantitative assessment of the carbocation/carbene character of the gold–carbene bond-Reference-Cited by-同舟云学术

Quantitative assessment of the carbocation/carbene character of the gold–carbene bond

Published:2015 Issue:31 Volume:44 Page:13999-14007
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Azzopardi Keith M.¹²³⁴⁵,Bistoni Giovanni⁶⁷⁸⁹¹⁰,Ciancaleoni Gianluca⁶⁷⁸⁹¹⁰,Tarantelli Francesco⁶⁷⁸⁹¹⁰^ORCID,Zuccaccia Daniele⁶⁷⁸⁹¹⁰,Belpassi Leonardo⁶⁷⁸⁹¹⁰

Affiliation:

1. Metamaterials Unit

2. Faculty of Science

3. University of Malta

4. Msida

5. Malta

6. Istituto di Scienze e Tecnologie Molecolari del CNR (CNR-ISTM)

7. c/o Dipartimento di Chimica

8. Biologia e Biotecnologie

9. Università degli Studi di Perugia

10. Perugia

Abstract

A simple geometrical parameter can be used to easily evaluate the Au → C1 back-donation.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT02183A

Reference59 articles.

1. When gold meets chiral Brønsted acid catalysts: extending the boundaries of enantioselective gold catalysis

2. Molecular Complexity from Polyunsaturated Substrates: The Gold Catalysis Approach

3. Dual Gold Catalysis

4. Gold catalysis in total synthesis—an update

5. Counterion Effects in Homogeneous Gold Catalysis

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