Improved emission of Yb(<scp>iii</scp>) ions in triazacyclononane-based macrocyclic ligands compared to cyclen-based ones-Reference-Cited by-同舟云学术

Improved emission of Yb(iii) ions in triazacyclononane-based macrocyclic ligands compared to cyclen-based ones

Published:2022 Issue:43 Volume:51 Page:16596-16604
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kiraev Salauat R.¹^ORCID,Mathieu Emilie¹^ORCID,Kovacs Daniel¹,Wells Jordann A. L.¹^ORCID,Tomar Monika¹,Andres Julien²^ORCID,Borbas K. Eszter¹^ORCID

Affiliation:

1. Department of Chemistry, Ångström Laboratory, Uppsala University, Box 523, 75120, Uppsala, Sweden

2. Chemistry and Chemical Engineering Section, Ecole Polytechnique Fédérale de Lausanne (EPFL), BCH 3311, CH-1015, Lausanne, Switzerland

Abstract

Yb(iii) complexes were synthesised from ligands with a 1,4,7-triazacyclononane (tacn) macrocyclic core. Tacn-based compounds equipped with 2 picolinate arms were more emissive than their tricarboxamide-cyclen analogues carrying the same antenna.

Funder

Vetenskapsrådet

Carl Tryggers Stiftelse för Vetenskaplig Forskning

Knut och Alice Wallenbergs Stiftelse

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT02266D

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