Ligand-directed assembly of trinuclear and one-dimensional heterotrimetallic CuIILnIIIFeIIIcomplexes: unusual antiferromagnetic CuIIFeIIIcoupling via cyano bridges
Author:
Affiliation:
1. Department of Chemistry
2. Tsinghua University
3. Beijing 100084
4. P. R. China
5. Beijing National Laboratory for Molecular Sciences
6. Center for Molecular Science
7. Institute of Chemistry
8. Chinese Academy of Sciences
9. Beijing 100190
Abstract
Rare phenoxo- and cyano-bridged CuLnFe trinuclear complexes were prepared. The 1D Cu2DyFe complex displays both single-chain magnetic properties and the intrachain Cu(ii)–Fe(iii) antiferromagnetic coupling.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2016/NJ/C6NJ01887D
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