Enantioselective synthesis of 3a-azido-pyrroloindolines by copper-catalyzed asymmetric dearomative azidation of tryptamines

Author:

Lin Cheng-Zhou1,Jiang Ling-Feng1,Zhang Guang-Yi1,Zhou Fang-Shuai1,Wu Shao-Hua1,Cao Jing1,Deng Qing-Hai1ORCID

Affiliation:

1. The Education Ministry Key Lab of Resource Chemistry, Shanghai Key Laboratory of Rare Earth Functional Materials, and Shanghai Frontiers Science Center of Biomimetic Catalysis, Shanghai Normal University, Shanghai 200234, P. R. China

Abstract

A facile strategy for the construction of enantioenriched 3a-azido-pyrroloindolinesviaa copper-catalyzed asymmetric dearomative azidation of tryptamines is presented.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Shanghai

Ministry of Education of the People's Republic of China

International Joint Laboratory of Resource Chemistry

Higher Education Discipline Innovation Project

Shanghai Engineering Technology Research Center

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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