Optical resolution of 1,16-dihydroxytetraphenylene by chiral gold(<scp>iii</scp>) complexation and its applications as chiral ligands in asymmetric catalysis-Reference-Cited by-同舟云学术

Optical resolution of 1,16-dihydroxytetraphenylene by chiral gold(iii) complexation and its applications as chiral ligands in asymmetric catalysis

Published:2022 Issue:16 Volume:13 Page:4608-4615
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Guo Jia¹,Xiong Wen-Bin¹,Ma Hao-Ran¹²,Fan Luoyi¹,Zhou You-Yun¹,Wong Henry N. C.¹²³^ORCID,Cui Jian-Fang¹^ORCID

Affiliation:

1. Department of Chemistry, Southern University of Science and Technology, 1088 Xueyuan Blvd, Shenzhen 518055, China

2. School of Science and Engineering, The Chinese University of Hong Kong (Shenzhen), 2001 Longxiang Blvd, Shenzhen 518172, China

3. Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong SAR, China

Abstract

Chiral gold(iii) complex was found to be a “golden key” to unlock (±)-1,16-dihydroxytetraphenylene (DHTP), leading to enantiopure DHTP in a large quantity. This approach provided convenient access to 2,15-diaryl (S)-DHTPs and phosphoramidites.

Funder

Southern University of Science and Technology

Innovation and Technology Commission

Chinese University of Hong Kong

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC00388K

Reference60 articles.

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2. Hydroxytetraphenylenes, a new type of self-assembling building block and chiral catalyst

3. Asymmetric Synthesis of Chiral Tetraphenylenes

4. Recent Developments and Applications of Chiral Tetraphenylenes

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