Employing transfer-dominated branching radical telomerisation (TBRT) and atom transfer radical polymerisation (ATRP) to form complex polyester-polymethacrylate branched-linear star copolymer hybrids <i>via</i> orthogonal initiation-Reference-Cited by-同舟云学术

Employing transfer-dominated branching radical telomerisation (TBRT) and atom transfer radical polymerisation (ATRP) to form complex polyester-polymethacrylate branched-linear star copolymer hybrids via orthogonal initiation

Published:2024 Issue:74 Volume:60 Page:10116-10119
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Dwyer Andrew B.¹²,Sandy William¹²^ORCID,Hern Faye Y.¹²,Penrhyn-Lowe Oliver B.¹²,McKeating Samuel¹²,Flynn Sean¹²,Wright Stephen¹²,Pate Sophie¹²,Chambon Pierre¹²,Rannard Steve P.¹²^ORCID

Affiliation:

1. Department of Chemistry, University of Liverpool, Crown Street, L69 7ZD, UK

2. Materials Innovation Factory, University of Liverpool, Crown Street, L69 7ZD, UK

Abstract

Consecutive free radical telomerisation and reversible-deactivation radical polymerisation reactions allow formation of branched polyester macroinitiators followed by arm growth leading to high molecular weight polyester-methacrylate star copolymers.

Funder

Engineering and Physical Sciences Research Council

University of Liverpool

Unilever

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC02142H

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