α-Ag2S nanoparticles: low-temperature syntheses, crystallisation pathway, and first operando luminescence measurements for sodium-ion battery applications

Author:

Ströh J.1,Ohrt L.1,Harder A.1,Collette Y.1,Liers L.1,Teotonio E.12,Novikov D.3,Khadiev A.3,Teske C. L.1,Terraschke H.14ORCID

Affiliation:

1. Institut für Anorganische Chemie, Christian-Albrechts-Universität zu Kiel, Max-Eyth-Str. 2, 24118 Kiel, Germany

2. Department of Chemistry, Federal University of Paraíba, 58051-970 João Pessoa, Paraíba, Brazil

3. DESY Photon Science, Notkestr. 85, 22607 Hamburg, Germany

4. Kiel Nano, Surface and Interface Science KiNSIS, Kiel University, Christian-Albrechts-Platz 4, 24118 Kiel, Germany

Abstract

In situ analyses provide new insights into the nucleation and growth of α-Ag2S, allowing fine tuning of their particle size, while operando luminescence measurements helped to reveal the conversion of α-Ag2S to Na(Ag3S2) and Ag during SIB cycling.

Funder

Fonds der Chemischen Industrie

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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