Synthesis and reactivity of heteroleptic zinc(i) complexes toward heteroallenes-Reference-Cited by-同舟云学术

Synthesis and reactivity of heteroleptic zinc(i) complexes toward heteroallenes

Published:2021 Issue:100 Volume:57 Page:13692-13695
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Li Bin¹^ORCID,Huse Kevin¹,Wölper Christoph¹,Schulz Stephan¹^ORCID

Affiliation:

1. Institute of Inorganic Chemistry and Center for Nanointegration Duisburg-Essen (CENIDE), University of Duisburg-Essen, 45117 Essen, Germany

Abstract

Heteroleptic zinc(i) complexes Cp*Zn–ZnL1/2 were synthesized and reactions of Cp*Zn–ZnL22 with t-BuNCO and organoazides RN3 proceeded with insertion into the Zn–Zn bond and formation of novel zinc carbamate, bis-hexazene, triazenide, and azide complexes 4–7.

Funder

Universität Duisburg-Essen

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC05617D

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