Intrinsic37/35Cl and18/16O isotope shifts in195Pt and103Rh NMR of purely inorganic Pt and Rh complexes as unique spectroscopic fingerprints for unambiguous assignment of structure-Reference-Cited by-同舟云学术

Intrinsic37/35Cl and18/16O isotope shifts in195Pt and103Rh NMR of purely inorganic Pt and Rh complexes as unique spectroscopic fingerprints for unambiguous assignment of structure

Published:2017 Issue:29 Volume:46 Page:9303-9315
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Koch Klaus R.¹²³⁴^ORCID,Engelbrecht Leon¹²³⁴

Affiliation:

1. Department of Chemistry and Polymer Science

2. Stellenbosch University

3. Matieland

4. South Africa

Abstract

The intrinsic¹ΔM(^37/35Cl) and¹ΔM(^18/16O) isotope shifts (M =¹⁹⁵Pt or¹⁰³Rh) visible in the NMR peak profile, of the [PtCl_n(H₂O)_6−n]⁴⁻ⁿ, [PtCl_6−n(OH)_n]²⁻(n= 1−6), and [RhCl_n(H₂O)_6−n]³⁻ⁿ(n= 3−6) complexes in aqueous solution at 293 K, unambiguously characterize their structures.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01722G

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