Origin of copper dissolution under electrocatalytic reduction conditions involving amines-Reference-Cited by-同舟云学术

Origin of copper dissolution under electrocatalytic reduction conditions involving amines

Published:2024 Issue:35 Volume:15 Page:14485-14496
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Guan Yani¹^ORCID,Kümper Justus²^ORCID,Mürtz Sonja D.²^ORCID,Kumari Simran¹,Hausoul Peter J. C.²^ORCID,Palkovits Regina²³^ORCID,Sautet Philippe¹⁴^ORCID

Affiliation:

1. Department of Chemical and Biomolecular Engineering, University of California Los Angeles, Los Angeles, CA 90095, USA

2. Chair of Heterogeneous Catalysis and Technical Chemistry, RWTH Aachen University, Worringerweg 2, 52074 Aachen, Germany

3. Institute for Sustainable Hydrogen Economy (INW-2), Forschungszentrum Jülich, Am Brainergy Park 4, 52428 Jülich, Germany

4. Department of Chemistry and Biochemistry, University of California Los Angeles, Los Angeles, CA 90095, USA

Abstract

Copper electrodes corrode using mixtures of acetone and methylamine even under reductive potential conditions. Simulations explain this dynamical process from a microscopic perspective through the formation of a surface Cu–amine complex.

Funder

Deutsche Forschungsgemeinschaft

Fachagentur Nachwachsende Rohstoffe

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC01944J

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