Modulation of the structural information in shape-defined heterocyclic strands: the case of a (pyridine-hydrazone)2pyrazine ligand

Author:

Thangavel Muthu Kumar12ORCID,Harrowfield Jack2ORCID,Bailly Corinne3,Karmazin Lydia3ORCID,Stadler Adrian-Mihail245ORCID

Affiliation:

1. Institut de Chimie, Université de Strasbourg, Strasbourg, France

2. Institut de Science et d'Ingénierie Supramoléculaires (ISIS), UMR 7006, CNRS – Université de Strasbourg, 8 Allée Gaspard Monge, 67000 Strasbourg, France

3. Service de Radiocristallographie, Université de Strasbourg, 1 Rue Blaise Pascal, 67000 Strasbourg, France

4. University of Strasbourg Institute for Advanced Study (USIAS), 5 Allée du Général Rouvillois, 67083 Strasbourg, France

5. Institut für Nanotechnologie (INT), Karlsruhe Institut für Technologie (KIT), 76344 Eggenstein-Leopoldshafen, Germany

Abstract

Metal ions (Ag+, Cd2+, Eu3+, Sm3+) and protons modulate the structural information of a pyrazine-based ligand, thus generating linear and bent conformations, associated to diprotonated forms, a polymeric architecture, rack-like complexes and a grid.

Funder

LabEx Chimie des Systèmes Complexes

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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