Synthesis and Cluster Structure Distortions of Biscarborane Dithiol, Thioether, and Disulfide
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Published:2024
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ISSN:1477-9226
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Container-title:Dalton Transactions
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language:en
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Short-container-title:Dalton Trans.
Author:
Riffle Jared R.,Hemingway Tyler M.,Smith Mark D.,Peryshkov Dmitry V.
Abstract
The synthesis and structural characterization of the first sulfur-containing derivatives of C,C-biscarborane {ortho-C2B10}2 cluster – thiol, thioether, and disulfide- is reported. The biscarboranyl dithiol (1-HS-C2B10H10)2 exhibits the exceedingly long intracluster...
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry