Effect of surfactant concentration on diffusion and microstructure in water-in-oil emulsions studied by low-field benchtop NMR and optical microscopy

Author:

D’Agostino Carmine12ORCID,Preziosi Valentina34ORCID,Caiazza Giuseppina3,Maiorino Maria Vittoria3,Fridjonsson Einar5,Guido Stefano34ORCID

Affiliation:

1. Department of Chemical Engineering and Analytical Science, The University of Manchester, The Mill, Sackville Street, Manchester, M13 9PL, UK

2. Dipartimento di Ingegneria Civile, Chimica, Ambientale e dei Materiali (DICAM), Alma Mater Studiorum – Università di Bologna, Via Terracini, 28, 40131 Bologna, Italy

3. Dipartimento di Ingegneria Chimica, dei Materiali e della Produzione Industriale, Università di Napoli Federico II, UdR INSTM, Piazzale Tecchio, 80, 80125, Napoli, Italy

4. CEINGE, Advanced Biotechnologies, Via Gaetano Salvatore 486, 80145 Napoli, Italy

5. Department of Chemical Engineering, The University of Western Australia, 35 Stirling Highway, Crawley, WA 6009, Australia

Abstract

In emulsions, at high surfactant concentration the formation of small droplets gives rise to a third compontenet in the PFG NMR attenuation plot which is attributed to both increased restriction and structuring effects near the droplet boundaries.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Chemistry

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