Experimental and theoretical insights into the <i>trans</i> influence of organo-sulfur and -selenium ligands in 5,6-membered palladium(<scp>ii</scp>) cationic pincer complexes based on iminophosphoranes-Reference-Cited by-同舟云学术

Experimental and theoretical insights into the trans influence of organo-sulfur and -selenium ligands in 5,6-membered palladium(ii) cationic pincer complexes based on iminophosphoranes

Published:2022 Issue:19 Volume:46 Page:9344-9356
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Rodríguez-Álvarez Aurora¹,González-Espinoza Cristina E.²^ORCID,Martínez-De-León Carla Gabriela¹,Carrillo-Tripp Mauricio³,Hô Minhhuy¹,Grévy Jean-Michel¹^ORCID

Affiliation:

1. Centro de Investigaciones Químicas, Instituto de Investigación en Ciencias Básicas y Aplicadas, Universidad Autónoma del Estado de Morelos, Avenida Universidad # 1001, Chamilpa, CP 62209 Cuernavaca, Morelos, Mexico

2. Université de Genève, Département de Chimie Physique 30, Quai Ernest-Ansermet, CH-1211 Genève 4, Switzerland

3. Biomolecular Diversity Laboratory, Centro de investigación y de Estudios Avanzados Unidad Monterrey, Vía del Conocimiento 201, PIIT, C.P. 66600 Apodaca, Nuevo León, Mexico

Abstract

The trans influence of organochalcogen ancillary ligands was assessed by experimental and DFT studies in 5,6-membered SNS and SNSe Pd(ii) pincers.

Funder

Consejo Nacional de Ciencia y Tecnología

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D2NJ00924B

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4. Design and development of POCN-pincer palladium catalysts for C–H bond arylation of azoles with aryl iodides

5. Mono- and binuclear palladacycles via regioselective C–H bond activation: syntheses, mechanistic insights and catalytic activity in direct arylation of azoles

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