Understanding of magnetic behavior of the pseudo-binary Co2−xNixZn11: in the light of crystal and electronic structures

Author:

Mondal Amit1ORCID,Kuila Sandip Kumar1ORCID,Pan Rahul1,Patel Shubham2ORCID,Buxi Krishnendu1ORCID,Saha Subhadip1,Ghanta Sivaprasad1,Avdeev Maxim34ORCID,Jana Partha Pratim1ORCID

Affiliation:

1. Department of Chemistry, IIT Kharagpur, Kharagpur 721302, India

2. Department of Physics, IIT Kharagpur, Kharagpur 721302, India

3. Australian Nuclear Science and Technology Organisation, New Illawarra Road, Lucas Heights, NSW 2234, Australia

4. School of Chemistry, The University of Sydney, Sydney 2006, Australia

Abstract

The Co2−xNixZn11 forms a γ-brass type structure, where the IT, OH, and CO sites are occupied by Zn, and the OT site is randomly distributed between Ni and Co. The para- to diamagnetism emerges with the increase of Ni content in the Co2−xNixZn11.

Funder

Science and Engineering Research Board

Indian Institute of Technology Kharagpur

Council of Scientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

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