Immobilization of 129I in nuclear waste glass matrixes synthesized under high-pressure conditions: an experimental study

Author:

Morizet Yann1ORCID,Hamon Jonathan2,La Carole1,Jolivet Valentin123,Suzuki-Muresan Tomo3,Paris Michael2ORCID

Affiliation:

1. Université de Nantes, Nantes Atlantique Universités, Laboratoire de Planétologie et Géodynamique de Nantes (LPG), UMR CNRS 6112, 2 rue de la Houssinière, 44322 Nantes Cedex, France

2. Université de Nantes, CNRS, Institut des Matériaux Jean Rouxel (IMN), 44000 Nantes, France

3. SUBATECH (IMT Atlantique, CNRS/IN2P3, Université de Nantes), 44307 Nantes Cedex 3, BP 20722, France

Abstract

Two recommendations are suggested for immobilizing 129I radioisotopes in high-pressure glasses: the use of an oxidized iodine form (I5+) instead of the reduced iodine form (I) and the use of a sodium rich composition instead of a calcium rich one.

Funder

Agence Nationale de la Recherche

Conseil Régional des Pays de la Loire

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Reference85 articles.

1. The geochemistry of iodine — a review

2. P. J.Coughtrey , D. J.Jackson and M. C.Thorne , Radionuclide distribution and transport in terrestrial and aquatic ecosystems , Balkema A. A. , Netherlands , vol. 1 , 1983

3. Increase of 129I in the environment

4. Estimate of European 129I Releases Supported by 129I Analysis in an Alpine Ice Core

5. Anthropogenic 129I in the atmosphere: Overview over major sources, transport processes and deposition pattern

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