Trimerisation of carbon suboxide at a di-titanium centre to form a pyrone ring system-Reference-Cited by-同舟云学术

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Trimerisation of carbon suboxide at a di-titanium centre to form a pyrone ring system

Published:2018 Issue:22 Volume:9 Page:5008-5014
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Tsoureas Nikolaos¹²³⁴⁵^ORCID,Green Jennifer C.²⁶⁷⁸⁵,Cloke F. Geoffrey N.¹²³⁴⁵^ORCID,Puschmann Horst⁹¹⁰¹¹⁵,Roe S. Mark¹²³⁴⁵,Tizzard Graham¹²¹³¹⁴¹⁵⁵

Affiliation:

1. School of Life Sciences

2. Department of Chemistry

3. University of Sussex

4. Brighton

5. UK

6. University of Oxford

7. Inorganic Chemistry Laboratory

8. Oxford OX1 3QR

9. OlexSys Ltd

10. Chemistry Department

11. Durham University

12. EPSRC National Crystallography Service

13. School of Chemistry

14. University of Southampton

15. Southampton SO17 1BJ

Abstract

Bis(pentalene)dititanium Ti₂(μ:η⁵,η⁵-Pn^†)₂ trimerises carbon suboxide (OCCCO) to form [{Ti₂(μ:η⁵,η⁵-Pn^†)₂}{μ-C₉O₆}], which contains a 4-pyrone core, via the monoadduct [Ti₂(μ:η⁵,η⁵-Pn^†)₂ (η²-C₃O₂)].

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC01127C

Reference51 articles.

1. Transformation of Carbon Dioxide with Homogeneous Transition-Metal Catalysts: A Molecular Solution to a Global Challenge?

2. Scalable carbon dioxide electroreduction coupled to carbonylation chemistry

3. 75 Years of oxo synthesis – The success story of a discovery at the OXEA Site Ruhrchemie

4. P. W. N. M. Van Leeuwen , Homogeneous Catalysis: Understanding the Art , Kluwer Academic , Dordrecht, The Netherlands , 2003

5. Ueber das Kohlensuboxyd. I

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