Stabilizing the structure of LiMn0.5Fe0.5PO4via the formation of concentration-gradient hollow spheres with Fe-rich surfaces

Author:

Ruan Tingting1234,Wang Bo12341ORCID,Wang Fei1234,Song Rensheng1234,Jin Fan1234,Zhou Yu1534,Wang Dianlong1234ORCID,Dou Shixue678910

Affiliation:

1. Harbin Institute of Technology

2. School of Chemical Engineering and Technology

3. 150001 Harbin

4. China

5. School of Materials Science and Engineering

6. Institute for Superconducting & Electronic Materials

7. Australian Institute of Innovative Materials

8. University of Wollongong

9. Wollongong

10. Australia

Abstract

A hollow concentration-gradient LiMn0.5Fe0.5PO4 sphere material is synthesized with a Mn-enriched inner shell to maximize the energy density and an Fe-enriched surface to improve the electrochemical activity and chemical stability.

Funder

National Natural Science Foundation of China

China Postdoctoral Science Foundation

Heilongjiang Provincial Postdoctoral Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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