The effect of coordination of alkanes, Xe and CO2 (η1-OCO) on changes in spin state and reactivity in organometallic chemistry: a combined experimental and theoretical study of the photochemistry of CpMn(CO)3-Reference-Cited by-同舟云学术

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The effect of coordination of alkanes, Xe and CO2 (η1-OCO) on changes in spin state and reactivity in organometallic chemistry: a combined experimental and theoretical study of the photochemistry of CpMn(CO)3

Published:2019 Issue: Volume:220 Page:86-104
ISSN:1359-6640
Container-title:Faraday Discussions
language:en
Short-container-title:Faraday Discuss.

Author:

Wu Xue¹²³⁴,Liu Zhen⁵⁶⁷⁸^ORCID,Murphy Thomas S.¹²³⁴^ORCID,Sun Xue Z.¹²³⁴,Hanson-Heine Magnus W. D.¹²³⁴,Towrie Michael⁹¹⁰¹¹¹²⁴,Harvey Jeremy N.¹³¹⁴¹⁵¹⁶^ORCID,George Michael W.¹²³⁴¹⁷^ORCID

Affiliation:

1. School of Chemistry

2. University of Nottingham

3. Nottingham

4. UK

5. State Key Laboratory of Chemical Engineering

6. East China University of Science and Technology

7. Shanghai 200237

8. China

9. Central Laser Facility, Research Complex at Harwell

10. Science and Technology Facilities Council

11. Rutherford Appleton Laboratory

12. Didcot

13. Department of Chemistry

14. KU Leuven

15. B-3001 Leuven

16. Belgium

17. Department of Chemical and Environmental Engineering

Abstract

A study is presented of ligand addition reactions of the fragment ³CpMn(CO)₂ formed upon photolysis of CpMn(CO)₃.

Funder

KU Leuven

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/FD/C9FD00067D

Reference88 articles.

1. Infrared spectra and photochemistry of the complex pentacarbonyliron in solid matrices at 4 and 20 K: evidence for formation of the complex tetracarbonyliron

2. Structure and reactions of matrix-isolated tetracarbonyliron(0)

3. Magnetic circular dichroism evidence for the paramagnetism of tetracarbonyliron(0): low-temperature matrix studies

4. Infrared spectrum of matrix isolated tricarbonyliron

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4. Formation of organometallic xenon complexes in conventional fluids: A time-resolved infrared (TRIR) study of the photochemistry of W(CO)5(4AcPyr) (4-AcPyr=4-Acetylpyridine) in perfluoromethylcyclohexane (PFMCH);Vibrational Spectroscopy;2020-05

5. A Structurally Characterized Cobalt(I) σ‐Alkane Complex;Angewandte Chemie International Edition;2020-02-20

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