Stabilization of Grignard reagents by a pillar[5]arene host – Schlenk equilibria and Grignard reactions-Reference-Cited by-同舟云学术

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Stabilization of Grignard reagents by a pillar[5]arene host – Schlenk equilibria and Grignard reactions

Published:2020 Issue:9 Volume:56 Page:1381-1384
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Shen Lingyi¹²³⁴⁵,Zhao Yanxia¹²³⁴⁵,Dai Dihua⁶⁷⁸⁹⁵,Yang Ying-Wei⁶⁷⁸⁹⁵^ORCID,Wu Biao¹²³⁴⁵^ORCID,Yang Xiao-Juan¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education

2. College of Chemistry and Materials Science

3. Northwest University

4. Xi’an 710069

5. China

6. International Joint Research Laboratory of Nano-Micro Architecture Chemistry (NMAC)

7. College of Chemistry

8. Jilin University

9. Changchun 130012

Abstract

Grignard reagents with linear alkyl chains are encapsulated and stabilized by pillar[5]arene while preserving their reactivity in Grignard reactions.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/C9CC08728A

Reference44 articles.

1. Cross-Coupling Reaction of Alkyl Halides with Grignard Reagents Catalyzed by Ni, Pd, or Cu Complexes with π-Carbon Ligand(s)

2. A New Type of Organo-Iron Compound

3. Über die Konstitution der Grignardschen Magnesiumverbindungen

4. Composition of grignard compounds. VII. Composition of methyl- and tert-butylmagnesium halides and their dialkylmagnesium analogs in diethyl ether and tetrahydrofuran as inferred from nuclear magnetic resonance spectroscopy

5. How Solvent Dynamics Controls the Schlenk Equilibrium of Grignard Reagents: A Computational Study of CH₃MgCl in Tetrahydrofuran

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1. Substrate and Product Selective Supramolecular Catalysis by Pillar[5]arene in the Alkylation of Primary Linear Amines with Allyl Bromide;ACS Catalysis;2024-10-10

2. Pillar[5]arene based artificial light-harvesting supramolecular polymer for efficient and recyclable photocatalytic applications;Chinese Chemical Letters;2024-09

3. Exploiting the Mechanical Bond Effect for Enhanced Molecular Recognition and Sensing;Advanced Materials;2024-01-09

4. Polydopamine modified by pillar[5]arene in situ for targeted chemo-photothermal cancer therapy;Chemical Communications;2024

5. An amphiphilic [2]biphenyl-extended pillar[6]arene: Synthesis, controllable self-assembly in water and application in cell-imaging;Chinese Chemical Letters;2023-08

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