Locking water molecules <i>via</i> ternary O–H⋯O intramolecular hydrogen bonds in perhydroxylated <i>closo</i>-dodecaborate-Reference-Cited by-同舟云学术

Locking water molecules via ternary O–H⋯O intramolecular hydrogen bonds in perhydroxylated closo-dodecaborate

Author:

Jiang Yanrong¹²^ORCID,Hu Zhubin²,Zhong Cheng³,Yang Yan²^ORCID,Wang Xue-Bin⁴^ORCID,Sun Zhenrong²,Sun Haitao²^ORCID,Liu Zhi¹,Peng Peng¹

Affiliation:

1. Center for Transformative Science, ShanghaiTech University, Shanghai 201210, China

2. State Key Laboratory of Precision Spectroscopy, East China Normal University, Shanghai 200241, China

3. College of Chemistry & Molecular Sciences, Wuhan University, Wuhan, Hubei 430072, China

4. Physical Sciences Division, Pacific Northwest National Laboratory, 902 Battelle Boulevard, P.O. Box 999, Richland, Washington 99352, USA

Abstract

The water molecule falls inside the claw formed by the ternary O–H bonds in B12(OH)122− associated with strong anionic hydrogen bonds.

Funder

National Natural Science Foundation of China

ShanghaiTech University

Shanghai Science and Technology Development Foundation

U.S. Department of Energy

Office of Science

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

Reference73 articles.

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