Nitrosyl linkage photoisomerization in heteroleptic fluoride ruthenium complexes derived from labile nitrate precursors-Reference-Cited by-同舟云学术

Nitrosyl linkage photoisomerization in heteroleptic fluoride ruthenium complexes derived from labile nitrate precursors

Published:2021 Issue:18 Volume:45 Page:8192-8202
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Mikhailov Artem A.¹²³⁴^ORCID,Komarov Vladislav Yu.¹²³⁴,Pishchur Denis P.¹²³⁴^ORCID,Schaniel Dominik⁵⁶⁷⁸⁹^ORCID,Kostin Gennadiy A.¹²³⁴^ORCID

Affiliation:

1. Nikolaev Institute of Inorganic Chemistry

2. Siberian Branch of the Russian Academy of Sciences

3. Novosibirsk 630090

4. Russian Federation

5. Université de Lorraine

6. CNRS

7. CRM2

8. UMR 7036

9. Nancy 54000

Abstract

Four complexes with trans-ON–Ru–F coordinate were synthesized from their nitrate precursors. Upon light irradiation, complexes I–III show reversible formation of highly stable linkage isomers MS2 which leads to a higher photogeneration temperature of MS1.

Funder

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/NJ/D1NJ01038G

Reference58 articles.

1. Molecular materials for switchable nonlinear optics in the solid state, based on ruthenium-nitrosyl complexes

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4. Photomagnetic effect in molecular magnets based on nitrosyl complexes of ruthenium and rare-earth ions

5. Photoinduced Nitrosyl Linkage Isomers Uncover a Variety of Unconventional Photorefractive Media

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