Tuning the electronic structure of gold cluster-assembled materials by altering organophosphine ligands-Reference-Cited by-同舟云学术

Tuning the electronic structure of gold cluster-assembled materials by altering organophosphine ligands

Published:2024 Issue:14 Volume:26 Page:10673-10687
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Sikorska Celina¹²^ORCID,Vincent Emma¹,Schnepf Andreas³^ORCID,Gaston Nicola¹^ORCID

Affiliation:

1. The MacDiarmid Institute for Advanced Materials and Nanotechnology, Department of Physics, The University of Auckland, 38 Princes Street, Auckland 1010, New Zealand

2. Faculty of Chemistry, University of Gdanśk, Fahrenheit Union of Universities in Gdanśk, 80-308 Gdanśk, Poland

3. Institut für Anorganische Chemie Universität Tübingen, Auf der Morgenstelle 18, D-72076 Tübingen, Germany

Abstract

Superatomic orbitals splitting and electronic structure tunability upon different organophosphine ligands insertion is demonstrated based on first-principles calculations.

Funder

Marsden Fund

H2020 Marie Skłodowska-Curie Actions

Narodowym Centrum Nauki

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D3CP04027E

Reference50 articles.

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2. N-Heterocyclic carbene derivatives to modify gold superatom characteristics. Tailorable electronic and optical properties of [Au₁₁(PPh₃)₇LCl₂]⁺ as a cluster from relativistic DFT

3. Superatomic S2 Silver Clusters Stabilized by a Thiolate–Phosphine Monolayer: Insight into Electronic and Optical Properties of Ag14(SC6H3F2)12(PPh3)8 and Ag16(SC6H3F2)14(DPPE)4

4. Ligand-protected gold/silver superatoms: current status and emerging trends

5. Atomic and electronic structure of gold clusters: understanding flakes, cages and superatoms from simple concepts

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