Fast and scalable solvent-free access to Lappert's heavier tetrylenes E{N(SiMe3)2}2 (E = Ge, Sn, Pb) and ECl{N(SiMe3)2} (E = Ge, Sn)-Reference-Cited by-同舟云学术

Fast and scalable solvent-free access to Lappert's heavier tetrylenes E{N(SiMe₃)₂}₂ (E = Ge, Sn, Pb) and ECl{N(SiMe₃)₂} (E = Ge, Sn)

Published:2023 Issue:44 Volume:14 Page:12477-12483
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Cabeza Javier A.¹^ORCID,Reynes Javier F.¹,García Felipe¹²^ORCID,García-Álvarez Pablo¹^ORCID,García-Soriano Rubén¹^ORCID

Affiliation:

1. Departamento de Química Orgánica e Inorgánica-IUQOEM, Centro de Innovación en Química Avanzada (ORFEO-CINQA) Universidad de Oviedo, 33071 Oviedo, Spain

2. School of Chemistry, Monash University, Clayton, Victoria 3800, Australia

Abstract

Lappert's heavier tetrylenes E{N(SiMe3)2}2 (E = Ge, Sn, Pb) have been efficiently prepared from GeCl2·(1,4-dioxane), SnCl2 or PbCl2 and Li{N(SiMe3)2} via a completely solvent-free one-pot mechanochemical route followed by sublimation.

Funder

Fundación para el Fomento en Asturias de la Investigación Científica Aplicada y la Tecnología

Ministerio de Ciencia e Innovación

Monash University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC02709K

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