Helical dinuclear 3d metal complexes with bis(bidentate) [S,N] ligands: synthesis, structural and computational studies-Reference-Cited by-同舟云学术

Helical dinuclear 3d metal complexes with bis(bidentate) [S,N] ligands: synthesis, structural and computational studies

Published:2024 Issue:43 Volume:53 Page:17608-17619
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Allen Jamie¹^ORCID,Saßmannshausen Jörg²^ORCID,Singh Kuldip¹,Kilpatrick Alexander F. R.¹^ORCID

Affiliation:

1. School of Chemistry, University of Leicester, University Road, Leicester, LE1 7RH, UK

2. Imperial College London, London, SW7 2AZ, UK

Abstract

A dinucleating [S,N] ligand with a flexible linker forms homobimetallic complexes with Fe, Co and Zn. These show a double-stranded helicate structure, stabilised by intramolecular π-π interactions, with homochirality at the two tetrahedral centres.

Funder

Royal Society of Chemistry

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT02395A

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