Two-dimensional metal–organic nanosheets composed of single-molecule magnets: structural modulation and enhanced magnetism utilizing the steric hindrance effect

Author:

Aratani Ikumi1,Horii Yoji1ORCID,Kotani Yoshinori2,Osawa Hitoshi2,Tanida Hajime3,Ina Toshiaki2,Watanabe Takeshi2,Yano Yohko F.4,Mizoguchi Akane1,Takajo Daisuke5,Kajiwara Takashi1ORCID

Affiliation:

1. Graduate School of Humanity and Science, Nara Women's University, Kitauoya-Higashimachi, Nara 630-8506, Japan

2. SPring-8/JASRI, Kouto, Sayo, Hyogo 679-5198, Japan

3. Materials Sciences Research Center, Sector of Nuclear Science Research, Japan Atomic Energy Agency, Sayo, Hyogo 679-5148, Japan

4. Department of Physics, Kindai University, 3-4-1 Kowakae, Higashiosaka City, Osaka 577-8502, Japan

5. Research Center for Thermal and Entropic Science, Graduate School of Science, Osaka University, 1-1 Machikaneyama-cho, Toyonaka, Osaka 560-0043, Japan

Abstract

Tuning the bulkiness of the single-molecule magnet (SMM) alters the structures of SMM-nanosheets, which results in enhanced perpendicular magnetic anisotropy and SMM properties.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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