Electrochemically-driven difunctionalization of the isocyanide and Mumm rearrangement cascade: expeditious synthesis of N-acyl–N-alkyl S-thiocarbamates-Reference-Cited by-同舟云学术

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Electrochemically-driven difunctionalization of the isocyanide and Mumm rearrangement cascade: expeditious synthesis of N-acyl–N-alkyl S-thiocarbamates

Published:2024 Issue:57 Volume:60 Page:7355-7358
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Bhati Kuldeep Singh¹,Sharma Siddharth¹^ORCID

Affiliation:

1. Department of Chemistry, Mohanlal Sukhadia University, Udaipur, 313001, India

Abstract

A novel electrochemical multicomponent reaction (e-MCR) synthesizes N-substituted S-thiocarbamate derivatives from isocyanides, thiols, and carboxylic acids via a difunctionalization and Mumm rearrangement cascade.

Funder

Science and Engineering Research Board

Rashtriya Uchchatar Shiksha Abhiyan

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC02287D

Reference23 articles.

1. The chemistry of thiocyanic esters

2. Structure–activity relations. Part 6. The alkaline hydrolysis of 3-methyl-5-methylidene- and 3,5-dimethylthiazolidine-2,4-diones. The addition of thiols to 3-methyl-5-methylidenethiazolidine-2,4-dione

3. Thiolcarbamates. Preparation and Molar Refractions1

4. A Safe and Efficient Method for Preparation of N,N'-Unsymmetrically Disubstituted Ureas Utilizing Triphosgene

5. A Concise Route to Structurally Diverse DMP 323 Analogues via Highly Functionalized 1,4-Diamines

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