Synthesis of optically active star polymers consisting of helical poly(phenylacetylene) chains by the living polymerization of phenylacetylenes and their chiroptical properties

Author:

Inaba Ayato1,Nishimura Tatsuya1ORCID,Yamamoto Masato1,Das Sandip2,Yurtsever Ayhan2ORCID,Miyata Kazuki2ORCID,Fukuma Takeshi2ORCID,Kawaguchi Seigo3ORCID,Kikuchi Moriya4ORCID,Taniguchi Tsuyoshi2ORCID,Maeda Katsuhiro12ORCID

Affiliation:

1. Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan

2. Nano Life Science Institute (WPI-NanoLSI), Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan

3. Department of Organic Materials Science, Graduate School of Organic Materials Science, Yamagata University, 4-3-16, Jonan, Yonezawa 992-8510, Japan

4. Faculty of Engineering, Yamagata University, 4-3-16, Jonan, Yonezawa 992-8510, Japan

Abstract

Star polymers with precisely controlled helical poly(phenylacetylene) arms were synthesized and exhibited chiral amplification compared with the corresponding linear polymers.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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