Spectroelectrochemical study of the reduction of 2-methyl-9H-thioxanthene-9-one and its S,S-dioxide and electronic absorption spectra of their molecular ions-Reference-Cited by-同舟云学术

Spectroelectrochemical study of the reduction of 2-methyl-9H-thioxanthene-9-one and its S,S-dioxide and electronic absorption spectra of their molecular ions

Published:2021 Issue:47 Volume:23 Page:26940-26947
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Odintsov Danila S.¹^ORCID,Shundrina Inna K.¹^ORCID,Gorbunov Dmitry E.²^ORCID,Gritsan Nina P.²^ORCID,Beckmann Jens³^ORCID,Shundrin Leonid A.¹^ORCID

Affiliation:

1. N.N. Vorozhtsov Institute of Organic Chemistry, Siberian Branch of Russian Academy of Sciences, Acad. Lavrentiev Avenue, 9, 630090, Novosibirsk, Russia

2. Institute of Chemical Kinetics and Combustion, Siberian Branch of Russian Academy of Sciences, 630090 Novosibirsk, Russia

3. Institute for Inorganic Chemistry and Crystallography, University of Bremen, 28359 Bremen, Germany

Abstract

Time-dependent DFT calculations interpret well the UV-VIS-NIR spectra of molecular ions of 2-methyl-thioxanthenones. The proposed empirical kinetic model successfully describes the time dependencies of optical density during reduction.

Funder

Deutsche Forschungsgemeinschaft

Ministry of Science and Higher Education of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP04464H

Reference35 articles.

1. Developing thioxanthone based visible photoinitiators for radical polymerization

2. Donor–Acceptor Type Thioxanthones: Synthesis, Optical Properties, and Two-Photon Induced Polymerization