Filling the gap between the quantum and classical worlds of nanoscale magnetism: giant molecular aggregates based on paramagnetic 3d metal ions

Abstract

The syntheses, structures and magnetic properties of giant molecular 3d and 3d/4f paramagnetic metal clusters are surveyed. Such complexes combine fascinating crystal structures, interesting magnetic properties and sizes comparable to those of classical magnetic nanoparticles providing a powerful bottom-up approach to nanoscale magnetic materials.